One of the challenges of individual dosimetry in Iran is the absence of standard radiation fields with different energies for calibration. For dosimetry in the photon fields, only the standard fields of Co-60 and Cs-137 sources, located in the (SSDL) can be utilized. This study aims to determine energy response of a personal thermoluminescence dosimeter (TLD) designed for determining the personal Dose-equivalent, Hp(10), in order to investigate whether the calibration curve in the Co-60 gamma field can be utilized for assessing the Dose-equivalent in the photon fields with different energies. To do this, first, the TLD dosimeters (an appropriate plastic badge including a TLD-100 chip) are irradiated with a few Hp(10) values using the Co-60 source in the Karaj SSDL. The badges are placed on a water phantom (slab), one meter distant from the source. Then, MCNP4C code is used to calculate the energy response at 662 keV and 1.25 MeV energies. Next, these responses are validated with the experimental data. Finally, the calculation is carried out for several other energies in the range of 20 keV to 1.25 MeV. Obtained results show that for the energies more than 400 keV, The response of the dosimeter is independent of the photon energy, within 10% uncertainty. On the other hand, for the energies smaller than 400 keV, a significant dependence on the energy is observed; such that in 40 keV the response is about 2 times larger than that at 1.25 MeV. Consequently, a method to reduce this uncertainty is needed.